Ionic Charge Effect on the Reduction Potential of Inert-type Metal Complex
- 1 August 1963
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 36 (8) , 917-919
- https://doi.org/10.1246/bcsj.36.917
Abstract
Current-potential curves of various oxalato complexes of chromium (III) were obtained at the dropping mercury electrode in acid or neutral aqueous solutions. The reduction potentials that were defined as potentials at \barl=\barll⁄10 were found to shift to more negative potentials with an increasing number of oxa-lates coordinated. The ionic charge effect on the reduction potentials was discussed in connection with the electrostatic interaction between the reacting species and the electrode.This publication has 5 references indexed in Scilit:
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