Synthesis of Methyl (Methyl D-and L-Idopyranosid)Uronates from myo-Inositol
- 1 September 1988
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 7 (3) , 555-570
- https://doi.org/10.1080/07328308808057550
Abstract
Methyl (methyl α-D-(9a), α-(9b), β-D-(10a), and β-L-(10b) idopyranosid)uronates were synthesized from myo-inositol. Baeyer-Villiger oxidation of the optically resolved inosose derivatives (3a and 3b) proceeded regioselectively to afford 4a and 4b in high yields, respectively. Ring-opening of the 7-membered hemiacetal-lactones (4a and 4b) with acid and subsequent deprotection gave the title compounds.This publication has 0 references indexed in Scilit: