Unusual Reactivity of “Proton Sponge” as a Hydride Donor to Transition Metals: Synthesis and Structural Characterization of Fluoroalkyl(hydrido) Complexes of Iridium(III) and Rhodium(III)

This publication has 22 references indexed in Scilit:

• Hydrogenolysis of Aliphatic Carbon−Fluorine Bonds in Fluoroalkyl−Iridium Complexes to Give Hydrofluorocarbons
  Journal of the American Chemical Society, 1999
• Deprotonation of the Transition Metal Hydride (η⁵-C₅Me₅)(PMe₃)IrH₂. Synthesis and Chemistry of the Strongly Basic Lithium Iridate (η⁵-C₅Me₅)(PMe₃)Ir(H)(Li)
  Organometallics, 1999
• Safe and Convenient Procedure for Solvent Purification
  Organometallics, 1996
• Chemical Redox Agents for Organometallic Chemistry
  Chemical Reviews, 1996
• Preparation of .beta.,.beta.-difluoro-.alpha.-(trifluoromethyl)styrenes by palladium-catalyzed coupling of aryl iodides with pentafluoropropen-2-ylzinc reagent
  The Journal of Organic Chemistry, 1993
• Analytical study of a series of substituted (2,2'-bipyridyl)(pentamethylcyclopentadienyl)rhodium and -iridium complexes with regard to their effectiveness as redox catalysts for the indirect electrochemical and chemical reduction of NAD(P)+
  Organometallics, 1991
• Oxidative addition of nitrogen-hydrogen bonds to iridium: synthesis and structure of (heterocyclic amine)iridium hydride complexes
  Inorganic Chemistry, 1990
• Electrophilic cleavage of carbon-fluorine bonds in hydrido trifluoromethyl complexes of platinum(II) by proton acids. Synthesis of hydrido carbene and hydrido carbonyl derivatives and x-ray structures of trans-PtH(CF3)(PPh3)2 (180 K) and trans-[PtH[cyclic](COCH2CH2O)(PPh3)2]BF4 (298 K)
  Inorganic Chemistry, 1989
• The proton sponge as nucleophile
  The Journal of Organic Chemistry, 1986
• Oxidative addition of soluble iridium and rhodium complexes to carbon-hydrogen bonds in methane and higher alkanes
  Pure and Applied Chemistry, 1984