New approach to the introduction of functionalised angular substituents via tricarbonyldieneiron complex intermediates
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 339-340
- https://doi.org/10.1039/c39770000339
Abstract
The reaction of tricarbonyl(4-methoxy-1-methylcyclohexadienyl)iron hexafluorophosphate (1), or tricarbonyl(2–8a-η-3-methoxyhexahydronaphthyl)iron tetrafluoroborate (5) with cyanide anion results in addition of the nucleophile to the more electron-deficient terminus of the dienyl system, forming quaternary centres and angularly substituted compounds (2) and (6), respectively.Keywords
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