Stereoselective Synthesis and Thermal Behavior of (Z)-Epoxyhexenynes: A Sinple and General Route to 2-Vinylfurans
- 1 January 1985
- journal article
- research article
- Published by CLOCKSS Archive in HETEROCYCLES
- Vol. 23 (11) , 2797-2802
- https://doi.org/10.3987/r-1985-11-2797
Abstract
An efficient approach for the synthesis of 2,3-disubstituted furans (2a-j/3a-j) is described by using the thermally induced rearrangement of epoxyhexenynes (1a-j) which are prepared by stereoselective synthesis of the (Z)-pentenynals 10 and subsequent Darzens reaction.Keywords
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