Asymmetric synthesis of α,α-dichlorosulphoxides from substituted thioacetates and sodium hypochlorite in β-cyclodextrin complexes
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 342-343
- https://doi.org/10.1039/c39890000342
Abstract
The reaction of β-cyclodextrin complexes of substituted thioacetates (1) with sodium hypochlorite in aqueous medium gives optically active α,α-dichlorosulphoxides (2) in good yields with an enantiomeric excess (e.e) of up to 53%.Keywords
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