CUPRIC ION-CATALYZED DIOXYGENATION OF 1,2-CYCLOHEXANEDIONES. A NONENZYMATIC ANALOG FOR QUERCETINASE DIOXYGENATION
- 5 April 1984
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 13 (4) , 635-638
- https://doi.org/10.1246/cl.1984.635
Abstract
1,2-Cyclohexanediones were found to be dioxygenated by molecular oxygen with the aid of cupric ion to afford 1,5-keto acids and carbon monoxide. The reaction proceeds possibly via an endoperoxide intermediate. Methyl α-hydroxyadipates were also formed as byproducts. The mechanism of oxygenation is discussed.Keywords
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