A novel catlytic synthesis of vinyl carboamtes from carbon dioxide, diethylamine, and alkynes in the presence of Ru3(CO)12

Abstract
The reaction of carbon dioxide, diethylamine, and hex-1-yne(1a) or phenylacetylene (1b), catalysed by Ru3(CO)12, gave the vinyl carbamates (2a), (3a) and (4a) or (2b) and (3b).

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