Optically active naphthalene–Cr(CO)3complexes via diastereoselective carbene annulation and haptotropic metal migration
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 2535-2536
- https://doi.org/10.1039/c39950002535
Abstract
Pentacarbonyl[(+)- and (–)-menthyloxycarbene] complexes of chromium react with 3, 3-dimethylbut-1-yne diastereoselectively to give optically active naphthalene–Cr(CO)3 complexes which upon warming undergo an intramolecular haptotropic migration of the metal fragment.Keywords
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