Formation of interwoven or partially interwoven metallomacrocyclic networks in copper(II) or zinc(II) complexes with N,N′-p-phenylenedimethylenebis(pyridin-4-one)
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1975-1977
- https://doi.org/10.1039/c39950001975
Abstract
X-Ray structural studies show that in the compounds [Cu2(p-XBP4)3(NO3)2](NO3)2·2H2O and [Zn2(p-XBP4)4](BF4)4·4H2O [p-XBP4 =N,N′-p-phenylenedimethylenebis(pyridin-4-one)] pyridone oxygen atoms bridge pairs of metal ions to form M2O2 units which, in turn, are linked by p-XBP4 bridges to produce complex arrays of, for Zn, 34- and 38-membered rings or, for Cu, 68-membered rings ‘threaded’ by interwoven p-XBP4 strands.Keywords
This publication has 10 references indexed in Scilit:
- Six Interpenetrating Quartz‐Like Nets in the Structure of ZnAu2(CN)4Angewandte Chemie International Edition in English, 1995
- Self‐Assembly of Molecular‐Sized BoxesAngewandte Chemie International Edition in English, 1995
- Chain and Large-Ring Polymeric Transition Metal and Lanthanide Complexes Formed by N,N'-Ethylenebis(pyrrolidin-2-one)Inorganic Chemistry, 1995
- 2,4,6‐Tri(4‐pyridyl)‐1,3,5‐triazine as a 3‐Connecting Building Block for Infinite NetsAngewandte Chemie International Edition in English, 1995
- A Three-Dimensional Warp-and-Woof Structure Interwoven by a Couple of Two-Dimensional Network Layers in the Crystal Structure of [trans-Cd(NH3)2{Ag(CN)2}2]nChemistry Letters, 1995
- [Mn(C18H16N2O2)3](ClO4)2: A Polymeric 34‐ and 68‐Membered Metallacyclic Network Forming a Novel Woven Polycatenated StructureAngewandte Chemie International Edition in English, 1995
- Assembly of porphyrin building blocks into network structures with large channelsNature, 1994
- Chemistry and Physics of a Molecular-Based Magnet Containing Three Spin Carriers, with a Fully Interlocked StructureJournal of the American Chemical Society, 1994
- Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(II) and 4,4'-BipyridineJournal of the American Chemical Society, 1994
- Interwoven two- and three-dimensional coordination polymers through self-assembly of Cu I cations with linear bidentate ligandsJournal of the Chemical Society, Chemical Communications, 1994