An Efficient Chiral Promoter in the Aldol-type Reaction. Chiral Diamine Coordinated Tin(II) Triflate–Dibutyltindiacetate Complex
- 1 October 1989
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (10) , 1757-1760
- https://doi.org/10.1246/cl.1989.1757
Abstract
An efficient chiral promoter, chiral diamine coordinated tin(II) triflate–dibutyltindiacetate complex, promotes the asymmetric aldol type reaction between both achiral silyl enol ethers derived from thioesters and a wide variety of aldehydes in high yields with perfect stereochemical control.Keywords
This publication has 2 references indexed in Scilit:
- Asymmetric Aldol-type Reaction between Both Achiral Ketene Silyl Acetals and Aldehydes by the Use of a Chiral PromoterChemistry Letters, 1989
- Perfect Stereochemical Control in the Synthesis of syn-α-Methyl-β-hydroxy Thioesters by Asymmetric Aldol Reaction of Silyl Enol Ethers with AldehydesChemistry Letters, 1989