NO(A 2Σ+–X2Π) chemiluminescence from the reaction C(1D)+NO2 at 300 K
- 15 September 1985
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 83 (6) , 2857-2859
- https://doi.org/10.1063/1.449236
Abstract
The metastable‐state atomic carbon C(1D,1S) as well as the ground‐state atomic carbon, C(3P), were produced at 300 K from the He(2 3S)+CO dissociative excitation by using a flowing afterglow apparatus. An intense ultraviolet chemiluminescence corresponding to the NO(A 2∑+–X2Π) transition was observed when NO2 was added, which was attributed to the reaction C(1D)+NO2 → NO(A 2∑+)+CO. The specific production of NO(A 2∑+) from the C(1D) reactants is explained by adiabatic correlation arguments.Keywords
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