Facile nBu4 NF Mediated Benzylation Of Congested 1,3-Diketones
- 1 January 1999
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 29 (1) , 117-122
- https://doi.org/10.1080/00397919908085742
Abstract
Facile benzylation of 1,3-diketones is mediated by nBu4NF in THF-water. The reaction conditions are mild, the performance is simple, and the yields are high. Importantly, no O-alkylation side reactions or subsequent retro-Claisen C-C-bond cleavage are observed even in sterically congested systems.Keywords
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