Insertion of norbornene into aryl–palladium(II) bonds: mechanistic aspects of the subsequent C–H activation
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1420-1423
- https://doi.org/10.1039/c39920001420
Abstract
The insertion of norbornene into the Pd–C bond of the cationic phenylpalladium(II) complex [PdPh(pmdien)]OTf (2, pmdien =N,N,N′,N′,N″-pentamethyldiethylenetriamine, OTf = trifluoromethanesulfonate) yields a 1 : 1 enantiomeric mixture of an ortho 2-exo-norbornyl-substituted phenylpalladium(II) compound via selective, intramolecular C–H activation of the phenyl ring.Keywords
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