Comparative study of chemical and polarization characteristics of Pd/Si and Pd/SiOx/Si Schottky-barrier-type devices

Abstract
The chemical nature of semitransparent (∼125 Å) palladium on silicon Schottky‐barrier‐type devices was determined by complementary AES and ISS techniques. Postdeposition analyses of metal‐semiconductor (MS) and metal–thin‐insulator–semiconductor (MIS) devices prepared without heat treatment showed that palladium silicide is formed in the MS structures, while the presence of an ultrathin (∼30 Å) purposefully grown semiconductor oxide film inhibits the chemical reaction between Pd and Si in the metal overlayer. Chemical bonding information extracted from the AES data was correlated with barrier‐height measurements obtained from capacitance‐vs‐voltage (CV) and current‐vs‐voltage (IV) electrical characteristics of these devices.