Carbon‐13 n.m.r. studies. 65—13C spectra of some tricyclo[3.2.1.02,4]octane derivatives
- 1 June 1977
- journal article
- research article
- Published by Wiley in Magnetic Resonance in Chemistry
- Vol. 9 (6) , 355-359
- https://doi.org/10.1002/mrc.1270090615
Abstract
The 13C n.m.r. spectra of 18 derivatives of the tricyclo[3.2.1.02,4]octanes have been determined. This series includes methyl, hydroxyl and oxo substituted examples to compare the effects of these substituents on the skeletal carbon shieldings with those observed for the corresponding norbornanes and bicyclo[3.2.1]octanes. In general, the trends are similar and the perturbations associated with closely neighboring groups follow a consistent pattern. The shielding data for the exo–exo and exo–endo isomers of tetracyclo[3.3.1.02,406,8]nonane are also reported.Keywords
This publication has 17 references indexed in Scilit:
- 13C nuclear magnetic resonance studies. 64. The 13C spectra of a variety of bicyclo[3.2.1]octanolsCanadian Journal of Chemistry, 1977
- 13C nuclear magnetic resonance studies. 55. A comparison of the stereochemical dependence of γ- and δ-substituent effects on 13C shieldings in several norbornanols and norbornenolsCanadian Journal of Chemistry, 1976
- Carbon-13 chemical shifts of 1-substituted norbornanesThe Journal of Organic Chemistry, 1976
- 13C nuclear magnetic resonance studies. 58. 13C spectra of a variety of bicyclo[2.2.2]octane derivatives. Further definition of the deshielding δ effectCanadian Journal of Chemistry, 1976
- Carbon-13 chemical shifts in bicyclo[2.2.2]octanesThe Journal of Organic Chemistry, 1976
- Carbon‐13 chemical shifts of bicyclo[3.2.1]octane and bicyclo[2.2.1]heptane derivativesMagnetic Resonance in Chemistry, 1976
- 13C Nuclear Magnetic Resonance Studies. Part 48. 13C Spectra of a Variety of Bicyclic KetonesCanadian Journal of Chemistry, 1975
- Carbon-13 nuclear magnetic resonance spectra of some epoxidesJournal of the Chemical Society, Perkin Transactions 2, 1975
- 13C Nuclear Magnetic Resonance Studies. 32. The 13C Spectra of Several Norbornyl DerivativesCanadian Journal of Chemistry, 1973
- Cyclopropane Synthesis from Methylene Iodide, Zinc-Copper Couple, and Olefins. III. The Methylene-Transfer ReactionJournal of the American Chemical Society, 1964