A New Synthesis of Methyl 3-Amino-3,4-dideoxy-β-D-xylo-hexopyranoside
- 1 December 1993
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 12 (8) , 1105-1115
- https://doi.org/10.1080/07328309308020120
Abstract
Benzylidenation of methyl β-D-glucopyranoside, followed by selective 3-O-tosylation, reductive acetal opening, chlorination, radical deoxygenation and transesterification, afforded methyl 2,3-anhydro-6-O-benzyl-4-deoxy-β-D-ribo-hexopyranoside 8. Subsequent epoxide opening with NaN3 and catalytic hydrogenation led to the title compound.Keywords
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