Pressure-Volume Isotherms ofbetween 1.5 and 3.8°K
- 15 June 1955
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 98 (6) , 1571-1575
- https://doi.org/10.1103/physrev.98.1571
Abstract
isotherms of gas have been measured at 3.786, 2.991, 2.161, 1.818, and 1.516°K. Values of the second virial coefficient, , derived from the data, are, respectively, -65.37, -86.25, -117.9, -142.3, and -168.0 cc/mole. For only the isotherms of 3.786 and 2.991°K was the third virial coefficient found to be significant. These values are 1132 and 1718 /, respectively. The measured are shown to be in satisfactory agreement with those calculated using a modified Slater-Kirkwood type potential, with constants chosen to give a good fit to the measured below 4°K.
Keywords
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