Relationship between Crystal Structure and Chemical Composition of PbTiO3 Thin Films Prepared by Sputter-Assisted Plasma CVD

Abstract
PbTiO3 thin films were prepared by sputter-assisted plasma chemical vapor deposition (CVD) on Pt-coated glass substrates at a substrate temperature of 500°C. As the source materials, a Pb metal target, TiCl4 gas and O2 gas were used. The crystal structures of the films changed from a pyrochlore phase to a perovskite one, and to a PbO (red) one with increasing Pb/Ti atomic ratio.

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