Catalytic Enantioselective Allylation of Ketones via a Chiral Indium(III) Complex
- 1 June 2005
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 7 (13) , 2743-2745
- https://doi.org/10.1021/ol051018n
Abstract
[reaction: see text] A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributylstannanes to ketones. The allylation of a variety of aromatic, alpha,beta-unsaturated and aliphatic ketones resulted in good yields and high enantioselectivities (up to 92% ee).Keywords
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