Amino-acids and peptides. Part 19. Conformational studies of the monamycins, a family of cyclohexadepsipeptide antibiotics
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 21,p. 2369-2376
- https://doi.org/10.1039/p19770002369
Abstract
Evidence derived largely from studies of monamycins D1 and H1 in solution using 1H n.m.r., 13C n.m.r., and i.r. spectroscopy supports a single conformation (Figure 6) for each congener. It incorporates a β-loop with hydrogen bonding of the NH groups of the Val residue to the carbonyl of the hydroxypiperazic acid residue.This publication has 1 reference indexed in Scilit:
- Amino-acids and peptides. Part XVIII. Studies relating to the synthesis and conformation of a novel bicyclic peptide systemJournal of the Chemical Society, Perkin Transactions 1, 1976