The Mechanism of Silicon−Hydrogen and Carbon−Hydrogen Bond Activation by Iridium(III): Production of a Silylene Complex and the First Direct Observation of Ir(III)/Ir(V) C−H Bond Oxidative Addition and Reductive Elimination

This publication has 18 references indexed in Scilit:

• Modeling the Proposed Intermediate in Alkane Carbon−Hydrogen Bond Activation by Cp*(PMe₃)Ir(Me)OTf: Synthesis and Stability of Novel Organometallic Iridium(V) Complexes
  Organometallics, 1999
• Reaction of Molybdenocene and Tungstenocene Derivatives with the Divalent Silicon Species SiN^tBuCHCHN^tBu and (C₅Me₅)₂Si
  Organometallics, 1999
• Silylenenickel(0) or Silyl(silylene)platinum(II) Complexes by Reaction of Si[(NCH₂Bu^t)₂C₆H₄-1,2] with [NiCl₂(PPh₃)₂], [Ni(cod)₂], or [PtCl₂(PPh₃)₂]
  Organometallics, 1998
• Generation of a Silylene Complex by the 1,2-Migration of Hydrogen from Silicon to Platinum
  Angewandte Chemie International Edition in English, 1998
• Electron Transfer Catalysis in the Activation of C-H Bonds by Iridium Complexes
  Organometallics, 1995
• Base-Free Silylene Complexes without .pi.-Donor Stabilization. Molecular Structure of [Cp*(PMe3)2Ru:SiMe2][B(C6F5)4]
  Journal of the American Chemical Society, 1994
• Silylene complexes from a stable silylene and metal carbonyls: synthesis and structure of [Ni{(Bu^tN–CHCH–NBu^t)Si}₂(CO)₂], a donor-free bis-silylene complex
  Journal of the Chemical Society, Chemical Communications, 1994
• A Fischer-type silylene complex of platinum: [trans-(Cy3P)2(H)Pt:Si(SEt)2]BPh4
  Journal of the American Chemical Society, 1993
• Synthesis and structure of a transition-metal-substituted silylene complex, (CO)4OsSi(STol-p)[Ru(.eta.5-C5Me5)(PMe3)2]
  Journal of the American Chemical Society, 1993
• Base-free silylene complexes [(.eta.5-C5Me5)(PMe3)2Ru:Si(SR)2]BPh4 (R = Et, p-MeC6H4)
  Journal of the American Chemical Society, 1990