Molecular collisions. XXI. Semiclassical approximation to atom-symmetric top rotational excitation
- 15 February 1974
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 60 (4) , 1313-1317
- https://doi.org/10.1063/1.1681196
Abstract
In Paper XIX of this series a distorted wave approximation to the T matrix for atom-symmetric top scattering was developed which is correct to first order in the part of the interaction potential responsible for transitions in the component of rotational angular momentum along the symmetry axis of the top. A semiclassical expression for this T matrix is derived by assuming large values of orbital and rotational angular momentum quantum numbers.Keywords
This publication has 2 references indexed in Scilit:
- Molecular collisions. XIX. The distorted wave approximation to atom-rigid symmetric top rotational excitationThe Journal of Chemical Physics, 1973
- Molecular Collisions. XII. Generalized Phase ShiftsThe Journal of Chemical Physics, 1970