Chemical shift correction to the Knight shift in beryllium
- 1 February 1983
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 27 (3) , 1906-1907
- https://doi.org/10.1103/physrevb.27.1906
Abstract
The Knight shift in beryllium has previously been measured to be small and negative, when referred to an aqueous solution of Be. Theoretical calculations assume a reference consisting of a bare nucleus shielded by the core electrons. With the use of a recent measurement of the shielded nuclear magnetic moment in free ions and published Hartree-Fock wave functions of Be and , it is shown that 20(4) ppm should be added to the experimental shifts in order to compare them with theory. This correction is of about the same magnitude as the measured Knight shift.
Keywords
This publication has 24 references indexed in Scilit:
- High resolution NMR in metallic samples of 27Al and 9BeSolid State Communications, 1973
- Theory of Hyperfine Properties of Beryllium and Magnesium MetalsPhysical Review B, 1970
- Calculation of the knight shift in berylliumPhysics Letters A, 1969
- Theory of Isotropic and Anisotropic Knight Shifts in BerylliumPhysical Review Letters, 1968
- Nuclear Magnetic Resonance in BerylliumPhysical Review B, 1967
- Nuclear Quadrupole Coupling, Knight Shift, and Spin-Lattice Relaxation Time in Beryllium MetalPhysical Review B, 1967
- Core-Polarization Contribution to the Knight Shift in Beryllium MetalPhysical Review B, 1966
- Calculation of the Knight-shift in metallic beryllium with an intermediate OPW-tight-binding methodPhysica, 1964
- Lowest valence-electron energy band and Knight shift in berylliumJournal of Physics and Chemistry of Solids, 1962
- The Effect of Electronic Paramagnetism on Nuclear Magnetic Resonance Frequencies in MetalsPhysical Review B, 1950