Difference Bands in the Raman Spectrum of Carbon Tetrachloride

Abstract
The difference bands of carbon tetrachloride are analyzed and it is found that, in the Raman spectrum at room temperature, the complex at 775 K is essentially all difference bands. This band has been previously assigned as the fundamental ν3, ν14 with a spacing of 28 K; the fundamental is present in the complex but its spacing is 15 K and it is weak. The difference bands of titanium tetrachloride are mentioned briefly.

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