Effect of grain boundaries in silicon on minority-carrier diffusion length and solar-cell efficiency

Abstract
The spatial variation of minority‐carrier diffusion length in the vicinity of a grain boundary for a polycrystalline silicon sheet has been measured by the use of the EBIC technique. The effect of such a variation on solar‐cell output has then been computed as a function of grain size. Calculations show that the cell output drops considerably for grain size smaller than three times the bulk diffusion length.

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