Study of thin corrosion films by in situ Raman spectroscopy combined with direct observation of nuclear reactions
- 1 July 1988
- journal article
- research article
- Published by Wiley in Surface and Interface Analysis
- Vol. 12 (7) , 419-423
- https://doi.org/10.1002/sia.740120710
Abstract
The rôle played by molybdenum in the passivation and corrosion of nickel alloys has been investigated by Raman spectroscopy and nuclear reaction analysis (NRA). NRA showed that the thickness of ‘passive’ films increased with the molybdenum content. When the molybdenum content in the alloy was high (greater than 10% atom), the films were formed of nickel molybdate NiMoO4, poorly crystallized and possibly hydrated.Keywords
This publication has 8 references indexed in Scilit:
- EXAFS study of passive films on Ni and Ni-Mo alloy electrodesSurface and Interface Analysis, 1988
- In‐Situ Raman Spectroscopy Combined with X‐Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe‐Cr Single CrystalsJournal of the Electrochemical Society, 1988
- Identification by In Situ Raman Spectroscopy of the Films Grown during the Polarization of Nickel in Sulfuric SolutionsJournal of the Electrochemical Society, 1986
- Anodic Films on Single Phase Ni-Mo AlloysCorrosion, 1984
- The Structure of Anodic Films Formed on Nickel and Nickel-13 w/o Molybdenum Alloy in pH 2.8 Sodium Sulfate SolutionCorrosion, 1984
- Vibrational spectrum of nickel molybdatePolyhedron, 1982
- Étude des propriétés optiques de films anodiques poreux de type NiOxSyPhysica Status Solidi (a), 1974
- Structure of the Aqueous Pertechnetate Ion by Raman and Infrared Spectroscopy. Raman and Infrared Spectra of Crystalline KTcO4, KReO4, Na2MoO4, Na2WO4, Na2MoO4·2H2O, and Na2WO4·2H2OThe Journal of Chemical Physics, 1964