The shock induced electrical polarization of water
- 15 November 1982
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 77 (10) , 5157-5164
- https://doi.org/10.1063/1.443692
Abstract
Experiment and theory for shock wave induced electrical polarization signals in water have now been carried out. The consistent interpretation of the results is (i) a shock front rise time of ∼ 10−12 s throughout the shock pressure range of 100 to 35 kbar (3.5 Pa) and probably down to at least 6 kbar, (ii) a transition in the source of the dominant polarization voltage to the alignment of unbonded dipole moments at ∼ 35 kbar, and (iii) in the unbonded region, the average contributing dipole is perfectly aligned in the direction of shock propagation. Additionally, in the unbonded pressure range, the calculated concentration of unbonded molecules is approximately equal to the hydrostatic equivalent concentration of ions.Keywords
This publication has 13 references indexed in Scilit:
- Thermal relaxation in a dense liquid under shock compressionPhysical Review A, 1981
- Reflectivity of a 5.8 kbar shock front in waterThe Journal of Chemical Physics, 1981
- Resistance to shock-front propagation in solidsJournal of Applied Physics, 1979
- Improved simulation of liquid water by molecular dynamicsThe Journal of Chemical Physics, 1974
- Effect of Pressure and Temperature on the Conductivity and Ionic Dissociation of Water up to 100 kbar and 1000°CThe Journal of Chemical Physics, 1969
- Electrical conductivity of water in shock compressionTransactions of the Faraday Society, 1966
- Shock-Induced Polarization in Plastics. I. TheoryJournal of Applied Physics, 1965
- Self-dissociation and protonic charge transport in water andProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1958
- Equation of State of Water to 250 KilobarsThe Journal of Chemical Physics, 1957
- Molecular association in liquids II. A theory of the structure of waterProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1951