Highly Practical “Ligand‐Free‐Like” Copper‐Catalyzed N‐Arylation of Azoles in Lower Nitrile Solvents
- 30 May 2008
- journal article
- research article
- Published by Wiley in Advanced Synthesis & Catalysis
- Vol. 350 (9) , 1253-1257
- https://doi.org/10.1002/adsc.200700535
Abstract
In lower nitrile solvents, the N‐arylation of azoles with aryl halides was achieved efficiently in the presence of copper powder without any additional ligands. Thus, the first nitrile type of monodentate ligand‐mediated, “ligand‐free‐like” copper‐catalyzed N‐arylation procedure was established.Keywords
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