New Arylruthenium(II) Complexes of the P,C,P‘-Coordinating Terdentate Monoanionic Aryl Ligands [C6H2(CH2PPh2)2-2,6-R-4]- (PCP-R-4; R = Ph, H). Synthesis of 16-Electron Species [RuIIX(PCP-R-4)(PPh3)] (X = Cl, I, OTf) and Their Reactivity toward the Neutral Terdentate N-Donor Ligand 2,2‘:6‘,2‘‘-Terpyridine (terpy)
- 24 December 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 15 (26) , 5687-5694
- https://doi.org/10.1021/om9603833
Abstract
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This publication has 28 references indexed in Scilit:
- VersatileN,C,NCoordination Behavior of a Monoanionic Aryldiamine Ligand in Ruthenium(II) Complexes: Syntheses and Crystal Structures of [RuII{C6H3(CH2NMe2)2-2,6}X(L)] (L = Norbornadiene, X = Cl, SO3CF3; L = PPh3, X = I) and [RuII{C6H3(CH2NMe2)2-2,6}(2,2‘:6‘,2‘‘-terpyridine)]ClOrganometallics, 1996
- New Soluble Polysiloxane Polymers Containing a Pendant Terdentate Aryldiamine Ligand Substituent Holding a Highly Catalytically Active Organometallic Nickel(II) CenterChemistry of Materials, 1994
- Copper(II)‐Mediated Oxidative Coupling of Bis(dimethylaminomethyl)arylruthenium Complexes to give [(terpy)RuIII(pincer‐pincer)‐RuIII(terpy)](CuCl2)4Angewandte Chemie International Edition in English, 1994
- Organonickel(II) complexes containing aryl ligands with chiral pyrrolidinyl ring systems; syntheses and use as homogeneous catalysts for the Kharasch addition reactionRecueil des Travaux Chimiques des Pays-Bas, 1994
- Carbon–hydrogen and C–X (X = Cl or SiMe3) bond activation. 1-Cyclopalladation and oxidation of some derivatives of 2-[(dimethylamino)methyl]naphthaleneJ. Chem. Soc., Dalton Trans., 1994
- Rigid five- and six-membered C,N,N'-bound aryl-, benzyl-, and alkylorganopalladium complexes: sp2 vs. sp3 carbon-hydrogen activation during cyclopalladation and palladium(IV) intermediates in oxidative addition reactions with dihalogens and alkyl halidesOrganometallics, 1993
- Insertion of norbornene into aryl–palladium(II) bonds: mechanistic aspects of the subsequent C–H activationJournal of the Chemical Society, Chemical Communications, 1992
- Influence of the amino substituents of potentially bis ortho chelating aryl ligands (2,6-{R1R2NCH2}2C6H3)- on the synthesis and properties of their organonickel(II) complexesInorganic Chemistry, 1991
- Tuning the reactivity of metals held in a rigid ligand environmentPure and Applied Chemistry, 1989
- Transition metal–carbon bonds. Part XLII. Complexes of nickel, palladium, platinum, rhodium and iridium with the tridentate ligand 2,6-bis[(di-t-butylphosphino)methyl]phenylJ. Chem. Soc., Dalton Trans., 1976