Dynamic scaling for the fragmentation of reactive porous media
- 24 August 1987
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 59 (8) , 888-891
- https://doi.org/10.1103/physrevlett.59.888
Abstract
We introduce a simple model for the consumption and fragmentation of a reactive porous medium, and investigate various distinct regimes of such processes. The model simulates the reaction-consumption process in a realistic way, and is capable of simulating the entire range of possible kinetic limitations. We show that a dynamic scaling governs the time evolution of the fragments distribution and calculate the critical exponents. They vary continuously with the reactivity of the porous medium. This dynamic scaling may also hold for the fragmentation of a system as a result of mechanical breakage, such as grinding of minerals, or stress-induced fragmentation of disordered solids, or of rocks and polymers.Keywords
This publication has 26 references indexed in Scilit:
- Chemical dissolution of a porous medium by a reactive fluidPhysical Review Letters, 1987
- Immobilization of enzymes in porous solids under restricted diffusion conditionsAIChE Journal, 1986
- A percolation model of catalyst deactivation by site coverage and pore blockageJournal of Catalysis, 1985
- Fractal Dimension in a Percolation Model of Fluid DisplacementPhysical Review Letters, 1985
- Dynamic Scaling for Aggregation of ClustersPhysical Review Letters, 1984
- Formation of Fractal Clusters and Networks by Irreversible Diffusion-Limited AggregationPhysical Review Letters, 1983
- Scaling of Kinetically Growing ClustersPhysical Review Letters, 1983
- Analysis of Char Combustion Including the Effect of Pore EnlargementCombustion Science and Technology, 1980
- The constrained brownian movement of spherical particles in cylindrical pores of comparable radiusJournal of Colloid and Interface Science, 1977
- Restricted Transport in Small Pores: A Model for Steric Exclusion and Hindered Particle MotionBiophysical Journal, 1974