An alternative to the magnus expansion in time-dependent perturbation theory
- 15 January 1985
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 82 (2) , 822-826
- https://doi.org/10.1063/1.448508
Abstract
An alternative to the Magnus expansion in time-dependent quantum mechanical perturbation theory is presented. An exponential form of the time-development operator, given as the exponential of a sum of products of integrals well known in time-dependent quantum mechanics, is derived from the standard perturbation expansion. The derivation is simple and the form of the terms in the exponential is so straightforward that the Nth order term can be written by inspection. The standard Magnus terms can be obtained by rearrangement of the terms of the new expansion probably easier than they can be obtained by iteration of the original equations. A proof by induction is presented to establish the form of the Nth term and it is shown how the new expansion terms relate to the Magnus terms. Some apparent differences between Magnus terms in the literature are resolved.Keywords
This publication has 14 references indexed in Scilit:
- Exponential time-dependent perturbation theory in rotationally inelastic scatteringThe Journal of Chemical Physics, 1983
- Study, extension, and application of Floquet theory for quantum molecular systems in an oscillating fieldPhysical Review A, 1983
- Application of the magnus expansion for high-order multiphoton excitationChemical Physics, 1981
- Analysis of multiple pulse NMR in solids. IIThe Journal of Chemical Physics, 1974
- Rotational spectral line broadening of OCS by noble gasesThe Journal of Chemical Physics, 1974
- Quantum Calculations of Planar Reactive H+H2. I. TheoryThe Journal of Chemical Physics, 1972
- Coherent Averaging Effects in Magnetic ResonancePhysical Review B, 1968
- Approach to High-Resolution nmr in SolidsPhysical Review Letters, 1968
- The formal power series for logexeyDuke Mathematical Journal, 1956
- On the exponential solution of differential equations for a linear operatorCommunications on Pure and Applied Mathematics, 1954