Hysteresis of the metal-insulator transition of ; evidence of the influence of microscopic texturation

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Abstract
Vanadium dioxide films have been deposited on silicon substrates by reactive RF cathodic sputtering from and targets. The optical measurements show a good contrast at the semiconductor-metal transition, but exhibit two kinds of hysteresis cycle: a narrow and symmetrical one, and a wider and asymmetrical one. We have mainly studied the microstructure of these samples by means of grazing-incidence x-ray diffraction at the LURE synchrotron radiation facility. We analysed in detail the intensities of the diffraction peak spectra and of the portions of diffraction rings. We found a clear relation between a narrow and symmetrical hysteresis cycle, and a (011) texture of the films. We attribute this result to an improvement in the cooperativity of the transition phenomena.