Insertion of alkenes into a palladium–acetyl bond
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1469-1470
- https://doi.org/10.1039/c39910001469
Abstract
A cationic acetylpalladium(II) complex cis-[Pd(COMe)(NCMe)(dppe)]+BF4 –2 exhibits extremely high reactivity toward simple alkenes including cyclopentene, cycloheptene and methyl acrylate to give the corresponding alkene-inserted complexes, which have been characterised by IR and NMR spectroscopy.Keywords
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