Highly Regioselective Functionalization of Aliphatic Carbon−Hydrogen Bonds with a Perbromohomoscorpionate Copper(I) Catalyst
- 15 January 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (6) , 1446-1447
- https://doi.org/10.1021/ja0291484
Abstract
The complex TpBr3Cu(NCMe) (1) is an excellent catalyst for the regioselective carbene transfer reaction to tertiary C−H bonds of hydrocarbons, at room temperature, using the readily available ethyl diazoacetate (EDA) as the carbene source.Keywords
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