Efficient and Chemoselective N-Nitrosation of Secondary Amines Under Mild and Heterogeneous Conditions with Sodium Nitrite and Oxalic Acid Two Hydrate
- 1 March 1999
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 29 (6) , 905-910
- https://doi.org/10.1080/00397919908086051
Abstract
Secondary amines can be quantitatively converted to their corresponding nitroso derivatives with a combination of oxalic acid and sodium nitrite in dichloromethane at room temperature.Keywords
This publication has 9 references indexed in Scilit:
- Reversibility of S-nitrosothiol formationChemical Communications, 1997
- S ‐ Nitroso Compounds, Formation, Reactions and Biological ActivityPublished by Wiley ,1996
- Nitric oxide release from S-nitrosothiols (RSNO) - the role of copper ionsTransition Metal Chemistry, 1996
- Rapid formation of a potent nitrosating agent by solvolysis of ionic nitrite in dichloromethaneJournal of the Chemical Society, Chemical Communications, 1987
- N-nitrosamines the phase-transfer mediated nitrosation of secondary amines with sodium nitrite and n-haloamidesTetrahedron Letters, 1984
- Fremy's salt (potassium nitrosodisulphonate): a nitrosating reagent for aminesJournal of the Chemical Society, Chemical Communications, 1983
- Nitrosyl‐Derivate des zweiwertigen Schwefels, II.: Das Nitrosyl‐äthylmercaptid, IIBerichte der deutschen chemischen Gesellschaft (A and B Series), 1926
- Nitrosyl‐Derivate des zweiwertigen Schwefels, I.: Das Nitrosyl‐äthylmercaptidBerichte der deutschen chemischen Gesellschaft (A and B Series), 1926
- CCXII.—The action of mercaptans on acid chlorides. Part II. The acid chlorides of phosphorus, sulphur, and nitrogenJournal of the Chemical Society, Transactions, 1909