Fluorinated and Hydrogenated Ethers Adsorbed at Metal Surfaces: A Surface Science Tribology Study
- 1 January 1990
- journal article
- research article
- Published by Taylor & Francis in Tribology Transactions
- Vol. 33 (4) , 557-562
- https://doi.org/10.1080/10402009008981989
Abstract
Fluorinated and hydrogenated ethers adsorbed at a metal surface are studied using surface science techniques. It is found that fluorinated ethers bond less strongly to both atomically rough and smooth ruthenium surfaces than hydrogenated analogs. The magnitude of the fluorinated ether-surface bond is further decreased if water is preadsorbed on the surface. For the hydrogenated ethers, 0.03 to 0.17 monolayer undergo decomposition, while fluorinated ethers do not decompose significantly.Keywords
This publication has 21 references indexed in Scilit:
- Surface chemistry of ketene on ruthenium(001). 2. Surface processes.The Journal of Physical Chemistry, 1988
- Surface chemistry of ketene on ruthenium(001). 1. Surface structuresThe Journal of Physical Chemistry, 1988
- Oxygenated fluorocarbons adsorbed at metal surfaces: chemisorption bond strengths and decompositionJournal of the American Chemical Society, 1987
- Adsorption of formaldehyde on the Ru(001) and Ru(001)-p(2 .times. 2)O surfacesJournal of the American Chemical Society, 1986
- Adsorption of acetone both on the clean ruthenium(001) surface and on the ruthenium(001) surface modified chemically by the presence of an ordered oxygen adatom overlayerJournal of the American Chemical Society, 1986
- The interaction of methanol with Ru(001)The Journal of Chemical Physics, 1984
- A comparison of weak molecular adsorption of organic molecules on clean copper and platinum surfacesSurface Science, 1984
- Adsorption and dehydrogenation of alcohols and ethers on platinum (111)Journal of Catalysis, 1982
- Decomposition of formic acid on Ru(001): An EELS search for a formic anhydride intermediateSurface Science, 1982
- Chemisorption and decomposition reactions of oxygen-containing organic molecules on clean Pd surfaces studied by UV photoemissionSurface Science, 1977