Normal coordinate analysis of the MNb2O6 series of columbite structure (M=Mg, Ca, Mn, Fe, Co, Ni, Cu, Zn, Cd)
- 1 August 1977
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 67 (3) , 1157-1163
- https://doi.org/10.1063/1.434968
Abstract
Normal coordinate analysis of the MNb2O6 series of columbite structure (M=Mg, Ca, Mn, Fe, Co, Ni, Cu, Zn, Cd) was carried out and the results obtained permitted the assignment of all the observed vibrational bands of the columbite series. It is also shown that the force fields of the columbite series are very similar when cations are changed. The variations are interpreted as due to the mass, the electronegativity, and the positions of the cations in the periodic table. The order of the bonds is also given.Keywords
This publication has 2 references indexed in Scilit:
- Magnetische Struktur von Columbit, FeNb2O6Zeitschrift für anorganische und allgemeine Chemie, 1971
- Spectres d’absorption infrarouge de niobates, tantalates et antimoniates de structure rutileJournal de Chimie Physique et de Physico-Chimie Biologique, 1970