The Formation and Electronic Relaxation of Intermolecular Exciplex in the Vapor Phase
- 1 November 1981
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 54 (11) , 3271-3273
- https://doi.org/10.1246/bcsj.54.3271
Abstract
The intermolecular exciplex formation and electronic relaxation of 1,4-dicyanonaphthalene (DCN) with pentamethylbenzene (PMB) in the vapor phase have been studied by means of nanosecond fluorescence spectroscopy. The exciplex formation and decay-rate constants were independent of the excitation energy, while the decay-rate constants of DCN fluorescence was dependent on the excitation energy. The rate constants of the exciplex formation and decay kinetics were discussed in comparison with the collisional relaxation rate of the upper vibrational states.This publication has 7 references indexed in Scilit:
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