Calcium-Mediated Intramolecular Hydroamination Catalysis
Top Cited Papers
- 1 February 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (7) , 2042-2043
- https://doi.org/10.1021/ja043576n
Abstract
The calcium-catalyzed intramolecular hydroamination of alkenes and alkynes is reported. The β-diketiminato complex [{HC(C(Me)2N-2,6-iPr2C6H3)2}-Ca{N(SiMe3)2}(THF)] affects catalytic cyclization of a range of aminoalkenes and aminoalkynes with activities that are broadly commensurate to those of established rare earth catalysts.Keywords
This publication has 14 references indexed in Scilit:
- Kinetic stability of heteroleptic (β-diketiminato) heavier alkaline-earth (Ca, Sr, Ba) amidesDalton Transactions, 2004
- Well-Defined Calcium Initiators for Lactide PolymerizationInorganic Chemistry, 2004
- Solution- and solid-state characterisation of a configurationally-stable β-diketiminato-supported calcium primary amideDalton Transactions, 2004
- Organolanthanide-Catalyzed HydroaminationAccounts of Chemical Research, 2004
- Scandium-Catalyzed Intramolecular Hydroamination. Development of a Highly Active Cationic CatalystOrganometallics, 2004
- Lactide polymerization by well-defined calcium coordination complexes: comparisons with related magnesium and zinc chemistryChemical Communications, 2002
- Intramolecular alkene hydroaminations catalyzed by simple amido derivatives of the Group 3 metalsTetrahedron Letters, 2001
- Structure of a Benzylcalcium Diastereomer: An Initiator for the Anionic Polymerization of StyreneOrganometallics, 2001
- A Unique Barium−Carbon Bond: Mechanism of Formation and Crystallographic CharacterizationJournal of the American Chemical Society, 1998
- Synthesis and Solution Behavior of (Tetraisopropylcyclopentadienyl)calcium Acetylide Complexes. Molecular Structure of {[(C3H7)4C5H]Ca(μ-C⋮CPh)(thf)}2Organometallics, 1996