Synthesis of Tetrasaccharide Repeating Unit of the K-Antigen fromKlebsiellaType-16
- 1 November 1995
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 14 (8) , 1153-1163
- https://doi.org/10.1080/07328309508005401
Abstract
Starting from L-fucose, D-glucose and lactose, methyl O-[2,3-di-O-benzoyl-4, 6-O-(4-methoxybenzylidene)-β-D-glucopyranosyl]-(1→4)-2,3-di-O-benzoyl-α-L-fucopyranoside and methyl O-(2,3,4,6-tetra-O-benzyl-β-D-galactopyranosyl)-(1→4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1→4)-O-(methyl 2,3-di-O-benzoyl-β-D-glucopyranosyluronate)-(1→4)-2,3-di-O-benzoyl-α-L-fucopyranoside were synthesized. Removal of protecting groups gave the tetrasaccharide repeating unit of the antigen from Klebsiella type-16 in the form of its methyl ester methyl glycoside.Keywords
This publication has 7 references indexed in Scilit:
- The 1,4-linked disaccharide of hyaluronan: synthesis of methyl 2-acetamido-2-deoxy-β-d-glucopyranosyl-(1 → 4)-β-d-glucopyranosiduronic acidCarbohydrate Research, 1994
- Synthesis of the methyl glycosides of a tri- and a tetra-saccharide related to heparin and heparan sulphateCarbohydrate Research, 1993
- Synthesis of 4-deoxy and 4-deoxy-4-halogeno derivatives of l-fucose as potential enzyme inhibitorsCarbohydrate Research, 1991
- Primary structure of the Klebsiella serotype 16 capsular polysaccharideCarbohydrate Research, 1977
- Synthesis of O-β-d-glucopyranosyl-(1→3)-O-α-l-fucopyranosyl-l-threonineCarbohydrate Research, 1976
- THE MERCAPTOLYSIS OF GLUCOSE AND GALACTOSE PENTAACETATESCanadian Journal of Chemistry, 1951
- Relations between Rotatory Power and Structure in the Sugar Group. XXXIII. The Alpha and Beta Methyl Pyranosides of L-Fucose (L-Galactomethylose) and their TriacetatesJournal of the American Chemical Society, 1939