Nature of copper in the new cuprate superconductors Pb2Sr2Ca1xLxCu3O8+δ

Abstract
Based on Cu K-edge absorption spectroscopy as well as Cu(2p3/2) and Cu(LVV) Auger spectroscopies it is shown that the recently discovered Pb2 Sr2 Ca1x Lx Cu3 O8+δ (L=Y or Lu) superconductors contain well-defined Cu1+ species in admixture with Cu2+. The proportion of Cu1+ is small in the nonsuperconducting samples with x=1, a feature which is uniquely different from that in YBa2 Cu3 O7δ.