Formation of Fe3(NCMe)(CO)9 during the reaction of Fe3(μ3-CMe)(CO)10X clusters with alkynes (X = no) or diazoalkanes (X = H). First examples of ethylidyne-nitrogen coupling to acetonitrile
- 1 June 1986
- journal article
- research article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 307 (1) , C5-C6
- https://doi.org/10.1016/0022-328x(86)80186-3
Abstract
No abstract availableKeywords
This publication has 7 references indexed in Scilit:
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- Coupling of ethylidyne and carnbonyl ligands leading to a µ3η2bonded propynolate anion induced by one-electron reduction of [Fe3(CO)9(µ3-CO)(µ3CMe)][PPh4]: X-ray crystal structure of [Fe3(CO)9(µ3, µ2-MeCCO)][PPh4]2Journal of the Chemical Society, Chemical Communications, 1984
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- Electrophilic attack on the [µ3-acetyl-C1(Fe1 : Fe2)O(Fe1 : Fe3)]nonacarbonyl-triangulo-triferrate(1–) anion by fluoroboric acid and methyl fluorosulphate. Carbon–oxygen bond cleavage to give µ3-ethylidyne and µ-methoxo-groups. X-Ray crystal structures of Fe3(CO)9(µ3-MeCO)(µ-H), Fe3(CO)9(µ3-CMe)(µ3-OMe), and Fe3(CO)9(µ3-CMe)(µ3-COMe)J. Chem. Soc., Dalton Trans., 1983
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- Reversible hydrogenation and dehydrogenation of cluster bound acimidoyl and alkylidenimido groups. Synthesis of complexes containing triply bridging nitrene and nitrile ligandsJournal of the American Chemical Society, 1979