The retarded energy shift and pair polarizabilities of interacting atoms in an external field
- 10 August 1980
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 40 (5) , 1089-1105
- https://doi.org/10.1080/00268978000102151
Abstract
The interaction energy of two atoms in the presence of an external electrostatic field is evaluated up to sixth order with the help of covariant field-theoretical perturbation theory. The divergent Feynman diagrams entering the calculation are resummed according to a systematic procedure that has been developed in a previous paper. The pair polarizability and first hyperpolarizability that give the response of the interacting atoms to the external field are subsequently obtained from the energy shift by virtue of a Hellmann-Feynman theorem. The retardation effects showing up in the pair polarizability are discussed in detail.Keywords
This publication has 16 references indexed in Scilit:
- Collision-induced polarizabilities of inert gas atomsMolecular Physics, 1978
- Retardation in the atomic pair polarizabilityChemical Physics Letters, 1977
- The coupling of intermolecular interactions to a static electric fieldMolecular Physics, 1974
- The polarizability of a pair of hydrogen atoms at long rangeChemical Physics Letters, 1973
- Long-Range Polarizability of the Helium DiatomThe Journal of Chemical Physics, 1971
- On the Theory of the Second Dielectric Virial CoefficientThe Journal of Chemical Physics, 1970
- Influence of molecular interaction on the clausius-mossotti function for nonpolar gasesChemical Physics Letters, 1967
- The dielectric constant of an imperfect non-polar gasTransactions of the Faraday Society, 1955
- On the theory of molecular polarization in gases: I. Effect of molecular interactions on the polarizability of spherical nonpolar moleculesPhysica, 1954
- The Influence of Retardation on the London-van der Waals ForcesPhysical Review B, 1948