Synthesis of the new tripodal ligand tris-[3-(2′-pyridyl)pyrazol-1-yl]hydroborate, and the crystal structure of its europium(III) complex
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 2751-2752
- https://doi.org/10.1039/c39940002751
Abstract
The new tripodal ligand tris-[3-(2′-pyridyl)pyrazol-1-yl]hydroborate (L–), comprising three N,N-bidentate chelating arms linked by the apical boron atom, has been synthesized; the crystal structure of [EuL(MeOH)2F][PF6] reveals the nine-coordinate metal lying within the hexadentate ligand cavity.Keywords
This publication has 18 references indexed in Scilit:
- Hexadentate N3O3 amine phenol ligands for Group 13 metal ions: evidence for intrastrand and interstrand hydrogen-bonds in polydentate tripodal amine phenolsInorganic Chemistry, 1993
- Chiral analogs of enterobactin with hydrophilic or lipophilic propertiesJournal of the American Chemical Society, 1993
- Stereoselectivity in chiral iron(III) and gallium(III) tris(catecholate) complexes effected by nonbonded weakly polar interactionsJournal of the American Chemical Society, 1993
- Electrospray mass spectrometry of the self-assembly of a capped polymetallic complexJournal of the Chemical Society, Chemical Communications, 1993
- Vanadium(V) complexes of 1,5,10-tris(2,3-dihydroxybenzoyl)-1,5,10-triazadecane and its analogsInorganic Chemistry, 1992
- The titanium(IV) complex of a hexadentate tricatechol ligand: synthesis, crystal structure and electrochemistryJournal of the Chemical Society, Chemical Communications, 1991
- Vanadium(III) complexes with VN3O3 co-ordination by sexidentate Schiff-base ligands: synthesis, spectra and redox activityJ. Chem. Soc., Dalton Trans., 1991
- Synthesis and Metal-Binding Properties of Polybipyridine Ligands Derived from Acyclic and Macrocyclic PolyaminesHelvetica Chimica Acta, 1990
- Syntheses and therapeutic potential of hydroxamic acid based siderophores and analogsChemical Reviews, 1989
- Ruthenium(II)-polypyridine cage complexes: luminescence and photochemical propertiesJournal of the American Chemical Society, 1988