Nuclear magnetic resonance studies of 1H in zirconium halide hydrides: Shielding tensors
- 15 May 1979
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 70 (10) , 4552-4556
- https://doi.org/10.1063/1.437277
Abstract
The magnetic shielding tensors and T*2’s of 1H have been determined at room temperature in ZrClH0.5, ZrBrH1.0, and ZrBrH0.5 utilizing multiple pulse NMR. In addition, stoichiometries have been determined by spin counting. Each proton shielding tensor exhibits a large anisotropy compared to those found in hydrocarbons and salts, and is similar to that found in ZrClH1.0. Site occupations of the protons in these ’’sandwichlike’’ compounds has been inferred from isotropic shifts and from anisotropies.Keywords
This publication has 8 references indexed in Scilit:
- Hydrogen location and diffusion in a two-dimensional metal: Proton magnetic resonance in metallic zirconium monohalide hydridesPhysics Letters A, 1978
- Zirconium monobromide, a second double metal sheet structure. Some physical and chemical properties of the metallic zirconium monochloride and monobromideInorganic Chemistry, 1977
- Utility of pulse nuclear magnetic resonance in studying protons in coalsThe Journal of Physical Chemistry, 1977
- NMR study of thorium hydride ()Physical Review B, 1977
- Reaction of hydrogen with the metallic zirconium monohalidesInorganic Chemistry, 1977
- Crystal structure of zirconium monochloride. A novel phase containing metal-metal bonded sheetsInorganic Chemistry, 1976
- Analysis of multiple pulse NMR in solids. IIThe Journal of Chemical Physics, 1974
- Enhanced resolution for solid state NMRThe Journal of Chemical Physics, 1973