Cyclopolymerization. II. Electron Spin Resonance Studies of the Free-Radical Reactions of Some Diolefins
- 1 January 1975
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 9 (1) , 115-124
- https://doi.org/10.1080/00222337508068650
Abstract
ESR spectra have been recorded for a number of radicals generated in a flow cell by interaction of diallylmalonic acid, diallyl ether, diallylamine, and related compounds with amino, hydroxyl, and phenyl radicals in aqueous solution. The results indicate that the radicals initially formed by homolytic addition at one of the double bonds in the diolefins rapidly undergo cyclization to afford product radicals containing five-membered rings.Keywords
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