Reaction of Ethyl Diazoacetate with Alkyl-Aromatic Substrates: Influence of the TpxCu Catalyst in the Addition versus Insertion Chemoselectivity (Tpx = Homoscorpionate)
- 5 December 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 23 (2) , 293-295
- https://doi.org/10.1021/om034156u
Abstract
No abstract availableThis publication has 10 references indexed in Scilit:
- Intermolecular C–H activation at benzylic positions: synthesis of (+)-imperanene and (−)-α-conidendrinTetrahedron: Asymmetry, 2003
- Bond Dissociation Energies of Organic MoleculesAccounts of Chemical Research, 2003
- Highly Regioselective Functionalization of Aliphatic Carbon−Hydrogen Bonds with a Perbromohomoscorpionate Copper(I) CatalystJournal of the American Chemical Society, 2003
- Catalytic Asymmetric Benzylic C−H Activation by Means of Carbenoid-Induced C−H InsertionsThe Journal of Organic Chemistry, 2002
- Intermolecular Copper-Catalyzed Carbon−Hydrogen Bond Activation via Carbene InsertionJournal of the American Chemical Society, 2002
- Carbomethoxychlorocarbene: Spectroscopy, Theory, Chemistry and KineticsJournal of the American Chemical Society, 2001
- A fluorous phase approach to rhodium-catalyzed carbenoid reactions with diazoacetatesTetrahedron Letters, 1999
- Photolysis studies of α-diazoamides the effect of carboxamide substituents on selectivity ratiosTetrahedron Letters, 1983
- Transition-metal-catalyzed reactions of diazo compounds. 2. Addition to aromatic molecules: catalysis of Buchner's synthesis of cycloheptatrienesThe Journal of Organic Chemistry, 1981
- Catalytic control of reactions of dipoles and carbenes; an easy and efficient synthesis of cycloheptatrienes from aromatic compounds by an extension of Buchner's reactionJournal of the Chemical Society, Chemical Communications, 1980