The Relative Intensities of Multiplet Transitions in Complex Spectra

From the wave functions of the multiplets of Slater's theory of complex spectra, the relative transition probabilities of multiplet transitions have been calculated for Russell-Saunders coupling for the electron configurations $p^{3}s-p^2{s}^2$, $p^{3}s-p^4$, $p^{2}s-p^3$, $p^{4}s-p^3{s}^2$, $p^4{s}^2-p^{5}s$, $p^{2}s-p{s}^2$, $p^{4}s-p^5$ and the quintet transitions of $d^{3}p-d^{3}s$. The calculated quintet transition probabilities of $d^{3}p-d^{3}s$ are compared with the values measured in Ti I.