The observation of a Pb–Li bond; synthesis, structure and model molecular orbital (MO) calculations on the monomeric Ph3Pb–Li·(pmdeta) complex [pmdeta =(Me2NCH2CH2)2NMe]
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1413-1415
- https://doi.org/10.1039/c39920001413
Abstract
The title compound has been synthesised by the cleavage reaction of Ph3Pb–PbPh3 with BunLi and has been shown to have a monomeric Pb–Li bonded structure in the solid state; ab initio calculations have been used to probe the nature of the early main group metal/heavy p block metal bonding involved.Keywords
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